The 1st pull off (on the high e string) occurs on the beat. If you count from the start of the pattern, it’s on beat 3 (of the 2nd measure).
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I find it useful to also utilise songs that incorporate some of the techniques that I am trying to learn. One of my favourite tabs for hammer on / pull off practice is the intro riff in Nirvanas’s The Man Who Sold the World, but there are many others to choose from. When I listen to the song I know what it should sound like and the rhythm to use. Then I know when I get it right.
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Omg it is so hard during the struming of that song. Ok I have a solid reason reach for this amazing song. I have been working the single string and it sounds so cool. I cheaked out Justins lesson as well. With the pinky whew. I will get there. 
I will keep working these riffs into suplements for this lesson for sure. Thank you Dave for this tip from my all time favorite band.
I am trying to have fun with this and experiment…
What would be your suggested chord progression to play in the background (with a looper pedal) while doing combinations from this scale?